Calcium hydroxide - Chemical substance, strong base, formula ( ) 2 . It is a white powder, poorly soluble in water.

Calcium hydroxide solution chemical formula. Calcium hydroxide structural chemical formula

L.A. Kazeko, I.N. Fyodorova

Calcium hydroxide: yesterday, today, tomorrow

Calcium hydroxide Ca(OH) 2 is a strong base, slightly soluble in water. A saturated solution of calcium hydroxide is called lime water and is alkaline. In air, limewater quickly becomes cloudy due to the absorption of carbon dioxide and the formation of insoluble calcium carbonate.

Calcium hydroxide (“slaked lime”) is a white, very fine powder, slightly soluble in water (1.19 g/l), solubility can be increased by glycerin and sucrose. Hydrogen index (pH) is about 12.5. Calcium hydroxide is very sensitive to contact with atmospheric carbon dioxide, which transforms it into calcium carbonate. The drug should be stored in sealed packaging away from light; it can be stored in a supersaturated aqueous solution (distilled water) in an airtight bottle.

The basis for the use of calcium hydroxide in endodontics was information about the etiology and pathogenesis of pulpitis and apical periodontitis. The most common cause of these diseases is microorganisms in the root canal system of the tooth. Kakehashi et al. (1965), Moller et al. (1981) showed in experiments that periapical inflammation and destructive processes around the apex of the tooth develop only with the participation of root canal microorganisms. Favorable factors for the existence of microflora are the complex anatomy of the root canals, the ability of bacteria to penetrate into the dentinal tubules to a depth of 300 microns, anaerobic development conditions, the ability to feed from living or necrotic pulp, salivary proteins, and periodontal tissue fluid. Thus, the quality of endodontic treatment is determined by the quality of disinfection of the root canal system.

Endodontic instrument breakage, root perforation, ledges, and overfilling or underfilling are considered to be the main causes of endodontic failure. However, in most cases, these errors do not affect the outcome of endodontic treatment until a concomitant infection occurs. Of course, gross errors prevent or make it impossible to complete intracanal procedures, but the chances successful treatment significantly increase if the infectious and toxic contents of the root canals are effectively removed before filling.

Microorganisms that survive instrumentation and irrigation quickly multiply and repopulate root canals that remain empty between visits. The likelihood of reinfection depends on the quality of root canal filling and the usefulness of the coronal restoration. However, in all cases where bacteria remain in the root canal system, there is a risk of further development of peri-apical changes.

In untreated teeth with primary intracanal infection, one or more species of bacteria are usually present, with no apparent predominance of facultative or anaerobic forms. In case of secondary infection if treatment fails, a mixed infection is present, with gram-negative anaerobic strains dominating.

Exist different opinions in a relationship required quantity stages of treatment for patients with periapical problems. Thus, some authors justify the need to treat infected root canals in several visits, using temporary intracanal dressings, which allows for the gradual and controlled destruction of microorganisms in them. Others suggest preventing the growth of remaining microorganisms by depriving them of nutrition and living space by fully debridement, disinfection, and 3D filling of the root canals during the first and only visit.

Anti-inflammatory and antibacterial activity of calcium hydroxide

Instrumental treatment of the root canal reduces the number of microorganisms by 100-1000 times, but their complete absence is observed only in 20-30% of cases. Antibacterial irrigation with 0.5% sodium hypochlorite solution increases this effect to 40-60%. Achieve complete disinfection of infected root canals even after complete mechanical cleaning and irrigation with antiseptic solutions is very difficult in practice. It is possible to destroy bacteria remaining in the root canal by temporarily filling the root canal with antimicrobial agents until the next visit. Such drugs must have wide range antibacterial action, be non-toxic and have physical and chemical properties allowing them to diffuse through the dentinal tubules and lateral canals of the tooth root system.

Calcium hydroxide is widely used as a temporary intracanal agent in endodontics, which decomposes into calcium ions and hydroxide ions in an aqueous solution. Basic biological properties hydroxide: bactericidal activity, anti-inflammatory properties, tissue solubility, hemostatic effect, inhibition of tooth tissue resorption, stimulation of bone regeneration processes.

Calcium hydroxide has bactericidal activity due to its high alkalinity and the release of hydroxide ions - highly active free radicals - in the aqueous environment. Their effect on bacterial cells is explained by the following mechanisms:

- damage to the cytoplasmic membrane of the bacterial cell, playing an important role in the preservation of the cell. It is the cell membrane that provides selective permeability and transport of substances, oxidative phosphorylation in aerobic strains, production of enzymes and transport of molecules for the biosynthesis of DNA, cellular polymers and membrane lipids. Hydroxide ions from calcium hydroxide cause lipid oxidation, which leads to the formation of free lipid radicals and the destruction of phospholipids, which are structural components of cell membranes. Lipid radicals initiate chain reaction, resulting in the loss of unsaturated fatty acids and cell membranes are damaged;

- protein denaturation due to the fact that the alkaline environment of calcium hydroxide causes the destruction of ionic bonds that provide the structure of proteins. In an alkaline environment, the polypeptide chains of enzymes are chaotically combined and transformed into disordered formations. These changes often lead to loss of biological enzyme activity and disruption of cellular metabolism;

- damage to microbial DNA, with which hydroxide ions react, causing its splitting and leading to damage to genes due to disruption of DNA replication. In addition, free radicals can independently cause destructive mutations.

The bactericidal effect of calcium hydroxide depends on the concentration of hydroxide ions, which is high only in the zone direct contact with the drug. When calcium hydroxide diffuses deeper into dentin, the concentration of hydroxide ions decreases due to the action of buffer systems (bicarbonate or phosphate), acids, proteins and CO 2, the antibacterial activity of the drug may be reduced or slowed down. Neutralization of high pH calcium hydroxide can also occur as a result of coronal microleakage, leakage of tissue fluid through the root apex, the presence of necrotic masses in the canal, and the production of acidic substances by microbes. In the root canal the pH is 12-12.5, in the adjacent dentin, where there is close contact with the hydroxide, the pH varies from 8 to 11, and in the depths of the dentin the pH values ​​are 7-9. The highest pH values ​​were obtained in the period from 7 to 14 days after adding an aqueous suspension of calcium hydroxide to the channel.

Microorganisms differ in their resistance to pH changes; most of them reproduce at pH 6-9. Some strains can survive at pH 8-9 and are usually the cause of secondary infection. Enterococci ( E. faecalis), resistant to pH 9-11, are not normally found in root canals or are present in small quantities in untreated teeth. They play an important role in unsuccessful endodontic treatment and are often (32-38% of cases) present in teeth with apical periodontitis.

One of the important components of the effective disinfectant effect of the drug in endodontics is its ability to dissolve and penetrate into the root canal system. Alkalis (NaOH and KOH) are highly soluble and can diffuse deeper than calcium hydroxide. These substances have pronounced antibacterial activity. But high solubility and active diffusion enhance the cytotoxic effect on the cells of the body. Due to their high cytotoxicity, they are not used in endodontics. Calcium hydroxide is biocompatible, since due to its low water solubility and diffusion, a slow increase in pH occurs, which is necessary to destroy bacteria localized in dentinal tubules and other hard-to-reach anatomical formations. Because of these features, calcium hydroxide is an effective but slow-acting antiseptic.

The time required for optimal root canal disinfection with calcium hydroxide has not yet been precisely determined. Clinical studies provide conflicting results. Cwikla et al. (1998) found that in 90% of cases there was no bacterial growth after 3 months of hydroxide use. In a study by Bystrom et al. (1999) calcium hydroxide effectively killed microorganisms within 4 weeks of use. Reit and Dahlen used the drug for 2 weeks - infection persisted in 26% of root canals. In an experiment by Basrani et al. After one week of using calcium hydroxide, bacteria remained in the canals in 27% of cases.

Mechanisms of resistance of microorganisms to the action of intracanal disinfectants

Factors that determine the resistance of microorganisms to the action of disinfectants and the ability to survive after the use of intracanal (temporary and permanent) filling materials:

Neutralization of the drug with buffer systems or bacterial cell products;

Insufficient exposure of the disinfectant in the root canal to destroy microorganisms;

Low antibacterial effectiveness of the drug against root canal microorganisms;

The effect of the drug on microorganisms is limited for anatomical reasons;

The ability of microorganisms to change their properties (genes) after a change environment.

An important mechanism of bacterial resistance is their existence in the form of a biofilm. Biofilm is a microbiological population (bacterial ecosystem) associated with an organic or inorganic substrate, surrounded by bacterial waste products. Various strains of microorganisms collected in a biofilm are capable of organizing associations for joint survival and have increased resistance to antimicrobial agents and protective mechanisms. Over 95% of naturally occurring bacteria are found in biofilms.

It is more difficult to destroy bacteria in biofilms than in planktonic suspensions unless the disinfectant has the ability to dissolve tissue. When re-treating infected teeth, calcium hydroxide may not be 100% effective in killing stubborn bacteria ( E. faecalis), which are able to reproduce between visits to the dentist. Of great importance is a complete preparation and cleansing of the canal from all microorganisms on the first visit (using copious rinses with sodium hypochlorite). Prevention of re-infection of the root canal is achieved by completely sealing the tooth crown using high-quality temporary fillings.

Effect of solvents on the antibacterial activity of calcium hydroxide

Substances used as a medium for calcium hydroxide have different water solubility. An optimal environment should not change the pH of calcium hydroxide. Many solvents do not have antibacterial activity, such as distilled water, saline, and glycerin. Phenol derivatives, such as paramonochlorophenol, camphor phenol, have pronounced antibacterial properties and can be used as a hydroxide medium. Calcium hydroxide with paramonochlorophenol has a long range of action and destroys bacteria in areas remote from the places where the paste is applied.

Siqueira et al. found that calcium hydroxide in saline does not destroy E. faecalis And F. nucleatum in the dentinal tubules within a week of use. And calcium hydroxide paste with paramonochlorophenol and glycerin effectively destroyed bacteria in the tubules, including E. faecalis, within 24 hours of use. That is, paramonochlorophenol enhances the antibacterial activity of calcium hydroxide.

The results of a study on the disinfection of dentinal tubules using three preparations of calcium hydroxide (Ca(OH) 2 in distilled water, Ca(OH) 2 with potassium iodide and Ca(OH) 2 with iodoform (Metapex)) showed that Ca(OH) 2 in in its pure form it is less effective in killing microbes in dentinal tubules. Growth of some microorganisms has been observed in calcium hydroxide channels ( E. faecalis, C. albicans) to a depth of 250 microns for 7 days. This is explained by the fact that Ca(OH) 2 has a low degree of permeability and its high pH (12) is partially neutralized by dentin buffer systems. Ca(OH) 2 with potassium iodide is more effective than pure hydroxide. But the Metapex paste (Ca(OH) 2 with iodoform) turned out to be the most effective: in addition E. faecalis it neutralized other microbes and penetrated into the tubules to a depth of more than 300 µm (Cwikla et al.).

Abdullah et al. (2005) studied the effectiveness of various intracanal agents (calcium hydroxide, 0.2% chlorhexidine, 17% EDTA, 10% povidone-iodine, 3% sodium hypochlorite) against strains E. faecalis, located in bacterial biofilms. As part of a biofilm E. faecalis in 100% of cases it was destroyed by 3% sodium hypochlorite after 2 minutes and 10% povidone-iodine after 30 minutes. Calcium hydroxide partially eliminated these bacteria.

Since some microorganisms, especially E. faecalis, are resistant to calcium hydroxide, its combination with other antimicrobial agents that increase its activity, for example with idoform, camphor paramonochlorophenol, is justified. Having low surface tension, fat-soluble phenols penetrate deep into tooth tissue.

In endodontics to widespread use Chlorhexidine is recommended as an irrigant and intracanal dressing, which is effective against many bacteria that cause endodontic infection. The chlorhexidine molecule, interacting with the phosphate groups of the bacterial cell wall, penetrates the bacterium and has an intracellular toxic effect.

Calcium hydroxide in combination with 2% chlorhexidine gel has increased antimicrobial activity, especially against resistant microorganisms. Chlorhexidine in gel form has such positive properties as low toxicity for periodontal tissues, viscosity, which allows it to retain active substances in constant contact with the walls of the root canal and dentinal tubules, water solubility. The combination of chlorhexidine gel and calcium hydroxide has been found to be highly effective against E. faecalis in infected root dentin. High pH (12.8) in the first two days increases the penetration ability of the drugs.

Effective against E. faecalis after 1, 2, 7 and 15 days of use of 2% chlorhexidine gel. According to Gomes et al., 2% chlorhexidine gel has greater antibacterial activity against E. faecalis than calcium hydroxide, but this ability is lost when used for a long time. This is confirmed by other studies, even when using chlorhexidine in the form of a solution or gel at concentrations of 0.05%, 0.2% and 0.5%. The combination of chlorhexidine and calcium hydroxide inhibits growth by 100%. E. faecalis after 1-2 days of contact.

Calcium hydroxide as a physical barrier

Secondary intracanal infections are caused by microorganisms that enter the canal during treatment, between visits or after dental treatment. The main sources of secondary infection: dental plaque on teeth, caries, infected endodontic instruments. Causes of infection between visits may include microleakage through a temporary filling due to its destruction; tooth fracture; delay in replacing a temporary filling with a permanent one, when the tooth remains open for drainage. Secondary infection allows the emergence of new, virulent microorganisms that cause acute periapical inflammation.

Intracanal preparations destroy bacteria remaining after chemomechanical treatment of the canal, and are also used as a physical and chemical barrier that prevents the proliferation of microorganisms and reduces the risk of reinfection from the oral cavity. Reinfection of the canal is possible due to the fact that the drug is dissolved by saliva, saliva seeps into the space between the medication and the walls of the canal. However, if a drug has an antibacterial effect, it will first be neutralized and only then will bacterial invasion occur.

To prevent reinfection, the sealing ability of calcium hydroxide is more important than its chemical activity, since it has low water solubility, dissolves slowly in saliva, and remains in the canal for long term, delaying the movement of bacteria towards the apex. Despite the use of solvents, calcium hydroxide acts as an effective physical barrier, destroying some of the remaining bacteria and preventing their growth, limiting the space for reproduction.

It is proposed as a reliable isolating barrier for various endodontic problems (perforation of the cavity bottom, tooth root, root resorption, etc.). new class materials - mineral trioxide aggregate (ProRut MTA). The basis of MTA is calcium compounds.

The influence of calcium hydroxide on the quality of permanent root canal filling

Before permanent obturation, calcium hydroxide is removed from the root canal using sodium hypochlorite, saline and endodontic instruments.

Lambrianidis et al. (1999) investigated the possibility of removing certain calcium hydroxide preparations from root canals: Calxyl (42% calcium hydroxide) and an aqueous suspension (95% calcium hydroxide). The percentage of calcium hydroxide did not affect the effectiveness of cleaning the root canal walls. Paste residues can affect the mechanical properties of the sealer and impair the apical seal. There is an opinion that it is impossible to completely remove the paste from the walls of the root canal.

Residual calcium hydroxide negatively affects the hardening of zinc oxide eugenol sealers, as it interacts with the eugenol of the paste to form calcium eugenolate. In the clinic, this may manifest itself as blocking the advancement of the gutta-percha pin along the entire working length of the canal. If calcium hydroxide residues are not completely removed, they become compacted apically or in the recesses of the canal, which mechanically interferes with effective canal filling, complicates apical sealing and can affect the outcome of endodontic treatment. It is preferable to remove the apical calcium hydroxide plug.

Calcium hydroxide is effectively removed from the canal walls hand tools with a sodium hypochlorite and 17% EDTA wash. Difficulties in cleaning root canals after temporary filling are caused by paste-forming substances and fillers, and not calcium hydroxide. Calcium hydroxide preparations water based(especially those preparing ex tempore) are absolutely devoid of these shortcomings. Moreover, calcium hydroxide-based sealers should be considered the materials of choice for permanent obturation of root canals after their temporary filling with calcium hydroxide.

Indications for temporary filling of root canals

The use of non-hardening pastes based on calcium hydroxide is indicated as a temporary intracanal agent for the treatment of acute forms of apical periodontitis, destructive forms of chronic apical periodontitis, cystogranulomas, radicular cysts, progressive root resorption, teeth with an unformed root apex in pediatric practice.

Method of using calcium hydroxide:

1) calcium hydroxide in powder form is mixed to a paste with distilled water or glycerin;

2) the paste is injected into a carefully instrumentally and medicinally treated root canal using a canal filler;

3) to ensure adherence to the root dentin, the paste is compacted with a paper pin and covered with an airtight bandage.

Features of the use of calcium hydroxide for different conditions of the apical periodontium. At acute forms of apical periodontitis temporary filling with calcium hydroxide aims to have an anti-inflammatory and antimicrobial effect. Calcium hydroxide is introduced into the root canal loosely, without compaction, first for a day, then again for 1-3-7 days, depending on the clinical picture. In case of acute periapical abscess, periostotomy is performed according to indications.

At chronic destructive processes in the apical periodontium The goal is to provide not only an anti-inflammatory and antimicrobial effect, but also to stimulate reparative processes in the bone. Calcium hydroxide is injected into the root canal with compaction to the walls for 3-8 weeks, the time of renewal of the material depends on the clinical picture. Treatment is designed for a period of 0.5 to 1 year, its duration depends on the degree of infection of the root canal, the body's resistance, the patient's age, and motivation to cooperate. Restoration of the zone of destruction of the apical periodontium continues after continuous filling of the root canal with a calcium hydroxide-based sealer for 3-5 years.

Filling teeth with apical periodontitis at the first visit does not eliminate acute inflammation. Resorption of cement and dentin persists even 9 months after filling. Moreover, in 80% of cases a chronic process is formed. If the canal after drainage was filled with calcium hydroxide for 7 days before obturation, the periapical defect was replaced with new bone tissue, although in 18.8% of cases the inflammation progressed.

Acute reactions during hermetic closure of the coronal cavity persisted in only 5% of teeth in the presence of a periapical abscess. A temporary dressing and sealed seal prevent re-infection of the canal and increase the success of conservative treatment to 61.1% (compared to 22.2% without an antibacterial dressing).

When calcium hydroxide is used as a temporary dressing, after 3 years complete bone regeneration is observed in 82% of periapical lesions even large size. In 18% of cases, bone defects remained or slightly decreased in size. The most active reduction in the size of the defect was observed in the first year of treatment. The first positive signs were detected on radiographs 12 weeks after the introduction of the Ca(OH) 2 bandage, and on digital radiographs already after 3-6 weeks.

"Yesterday" calcium hydroxide. Information materials, scientific articles about calcium hydroxide preparations 20-30 years ago convinced (and convinced) us of its unique abilities: pastes based on calcium hydroxide have a highly alkaline reaction, unlimited bactericidal action, and the ability to stimulate reparative processes in bone tissue.

The use of calcium hydroxide in endodontics has expanded the indications for conservative treatment of destructive processes in the apical periodontium. It is now possible to fully preserve teeth that were previously considered hopeless. "The biocompatibility of calcium hydroxide has made it a multivalent preparation adapted to almost all clinical situations encountered in endodontics". Recommendations have appeared on the mandatory stage of temporary filling of root canals during endodontic treatment: “This is useful!”

“Today” a baggage of clinical observations has been accumulated, which confirm very high efficiency calcium hydroxide (Fig. 1-4; from the authors’ own observations). High-quality implementation of all stages of endodontic treatment in combination with temporary filling of root canals with calcium hydroxide allows us to recognize this method of treatment as organ-saving.

But today in the dental literature the issues of the breadth of the antibacterial action of calcium hydroxide preparations, targeted effects on the most resistant and aggressive strains of microorganisms that cause the development of periapical foci of destruction, re-infection and the development of exacerbations are discussed.

So, A.A. Antanyan writes: “Multilateral analysis scientific literature recent years(2003-2006) showed that calcium hydroxide has many disadvantages that call into question its routine and widespread use in endodontics. In modern endodontics, the most important is complete preparation, cleansing the canal from infection on the first visit (using copious rinses with sodium hypochlorite) and preventing re-infection of the canal by fully sealing the tooth crown using high-quality temporary fillings. Therefore, in many clinical situations, additional disinfection with calcium hydroxide is not necessary.”

"Tomorrow" calcium hydroxide. Experience in the clinical use of calcium hydroxide shows that the need for its use in endodontics cannot be justified solely by its antimicrobial effectiveness, which in past years was primarily responsible for the treatment outcome. With the advent of sensitive methods of microbiological research, with the expansion of the range of highly effective means for irrigation of root canals, the possibilities and properties of calcium hydroxide as a material for temporary filling can be rethought and reevaluated. But not discounted! In difficult clinical situations involving endodontic treatment and re-treatment of teeth, thanks to calcium hydroxide preparations, it is possible to preserve the patient’s teeth and health.

LITERATURE

1. Antanyan A. A.// Endodontics today. - 2007. - No. 1. - P. 59-69.

2. Beer R., Bauman M.A. Illustrated guide to endodontology. - M., 2006. - 240 p.

3. Glinka N.L. general chemistry: Textbook. manual for universities. - 20th ed., rev. / Ed. Rabinovich V.A. - L., 1979. - P. 614-617.

4. Gutman J.L., Dumsha T.S., Lovdel P.E. Solving problems in endodontics: Prevention, diagnosis and treatment / Transl. from English - M., 2008. - 592 p.

5. Poltavsky V.P. Intracanal medicine: Modern methods. - M., 2007. - 88 p.

6. Simakova T.G., Pozharitskaya M.M., Sinitsyna V.I.// Endodontics today. - 2007. - No. 2. - P. 27-31.

7. Solovyova A.B.// Dentsplay News. - 2003. - No. 8. - P. 14-16.

8. Kholina M.A.// Dentplay News. - 2007. - No. 14. - pp. 42-45.

9. Abdullah M., Yuan-Ling N., Moles D., Spratt D.// J. Endod. - 2005. - V. 31, N 1. - P. 30-36.

10. Allais G.// New in dentistry. - 2005. - No. 1. - P. 5-15.

11. Athanassiadis B., Abbott P.V., Walsh L.J.// Austr. Dent. J. - 2007. - Mar; 52 (Suppl 1). - S. 64-82.

12. Basrani B., Santos J.M., Tjäderhane L. et al. // Oral Surg. Oral Med. Oral Pathol. Oral radiol. Endod. - 2002. - Aug; 94(2). - P. 240-245.

13. Cwikla S., Belanger M., Giguere S., Vertucci F.// J. Endod. - 2005. - V. 31, N 1. - P. 50-52.

14. Ercan E., Ozekinci T., Atakul F., Gül K.// J. Endod. - 2004. - Feb; 30(2). - P. 84-87.

15. Gomes B., Souza S., Ferraz C.//Intern. Endod. J. - 2003 - V. 36. - P. 267-275.

16. Heckendorff M., HulsmannM. // New in dentistry. - 2003. - No. 5. - P. 38-41.

17. Lambrianidis T., Margelos J., Beites P.//Intern. Endod. J. - 1999. - V. 25, N 2. - P. 85-88.

18. Regan J.D., Fleury A.A.// J. Ir. Dent. Assoc. - 2006. - Autumn; 52 (2) - P. 84-92.

19. Sathorn C., Parashos P., Messer H.//Intern. Endod. J. - 2007. - V. 40, Issue 1. - P. 2-10.

20. Siqueira J.F., Paiva S.S., Rôças I.N.// J. Endod. - 2007. - May; 33(5). - P. 541-547.

Modern dentistry. - 2009. - No. 2. - P. 4-9.

Attention!The article is addressed to medical specialists. Reprinting this article or its fragments on the Internet without a hyperlink to the source is considered a violation of copyright.

inorganic compound, calcium alkali. Its formula is Ca(OH) 2. Since this substance has been known to mankind since ancient times, it has traditional names: slaked lime, lime water, lime milk, fluff.

Fluff is a finely ground powder. Lime milk is an aqueous suspension of alkali, an opaque white liquid. Lime water is a clear aqueous solution of alkali obtained after filtering lime milk.

Slaked lime is named after its production method: quicklime (calcium oxide) is poured with water (quenched).

Properties

Fine crystalline powder white, without smell. Very poorly soluble in water, insoluble in alcohol, easily soluble in dilute nitric and hydrochloric acids. Fireproof and even prevents fire. When heated, it decomposes into water and calcium oxide.

Strong alkali. It enters into neutralization reactions with acids to form salts - carbonates. When interacting with metals, explosive and flammable hydrogen is released. Reacts with carbon oxides (IV) and (II), with salts.

The reaction of producing calcium hydroxide by the “quenching” method occurs with a large release of heat, the water begins to boil, the caustic solution is sprayed in different directions - this must be taken into account when working.

Precautionary measures

Contact of dry powder particles or drops of calcium hydroxide solution on the skin causes irritation, itching, chemical burns, ulcers, and severe pain. Damage to the eyes can cause vision loss. Ingestion of the substance causes a burn to the mucous membrane of the throat, vomiting, bloody diarrhea, a sharp decrease in pressure, damage internal organs. Inhaling dust particles can cause throat swelling that makes breathing difficult.

Before calling " Ambulance»:
- in case of poisoning, give the victim milk or water to drink;
- if the chemical gets into the eyes or skin, the damaged area must be washed big amount water for at least a quarter of an hour;
- if the reagent is accidentally inhaled, the victim must be removed from the room and provided with access to fresh air.

Work with calcium hydroxide in well-ventilated areas using protective equipment: rubber gloves, safety glasses and respirators. Chemical experiments must be carried out in a fume hood.

Application

— In the construction industry, a chemical reagent is added to binding solutions, plaster, whitewash, and gypsum solutions; based on it they are made sand-lime brick and concrete; it is used to prepare the soil before laying road surfaces. Whitewashing wooden parts of structures and fences gives them fire-resistant properties and protects them from rotting.
— For neutralization of acid gases in metallurgy.
— For the production of solid oils and oil additives — in the oil refining industry.
- In the chemical industry - for the production of sodium and potassium alkalis, bleach (bleach), calcium stearate, organic acids.
— In analytical chemistry, lime water serves as an indicator carbon dioxide(absorbing it, it becomes cloudy).
— Using calcium hydroxide, wastewater and industrial waters; neutralize the acids of water entering water pipes to reduce its corrosive effects; remove carbonates from water (soften water).
— Using Ca(OH) 2, hair is removed from skins in tanning.
— Food additive E526 in the food industry: acidity and viscosity regulator, hardener, preservative. It is used in the production of juices and drinks, confectionery and flour products, marinades, salt, and baby food. Used in sugar production.
— In dentistry, lime milk is used to disinfect root canals.
- For the treatment of acid burns - in medicine.
— In agriculture: a means for regulating soil pH; as a natural insecticide against ticks, fleas, and beetles; for the preparation of a popular fungicide " Bordeaux mixture"; for whitewashing tree trunks from pests and sunburn; as an antimicrobial and antifungal drug for storing vegetables in warehouses; How mineral fertilizer.
— Calcium hydroxide reduces the electrical resistance of the soil, so it is used to treat the soil when installing grounding.
— The chemical reagent is used in the production of hard rubber, brake linings, and hair removal creams.

You can buy slaked lime at a good price, retail and wholesale, with delivery or pickup at the Prime Chemicals Group chemical store.

74.093 g/mol
Physical properties
Density of matter 2.211 g/cm³
Condition (standard condition) white crystals
Thermal properties
Melting temperature 512 °C
Chemical properties
Solubility in water 0.185 g/100 ml
Classification
CAS number

Trivial names

  • slaked lime - since it is obtained by “quenching” (that is, interacting with water) “quicklime” calcium oxide;
  • lime water- transparent (close to saturated) aqueous solution;
  • lime milk- aqueous suspension.
  • fluffy- dry calcium hydroxide.

Often called simply lime or lime(also called calcium oxide).

Receipt

It is obtained by reacting calcium oxide (quicklime) with water (the process is called “slaking lime”):

CaO + H 2 O → Ca(OH) 2

This reaction is exothermic and releases 16 kcal (67 kJ) per mole.

Properties

Appearance: white powder, slightly soluble in water:

Calcium hydroxide is a fairly strong base, which is why the aqueous solution is alkaline.

Like all hydroxides, it reacts with acids (see neutralization reaction) to form the corresponding calcium salts:

for the same reason, a solution of calcium hydroxide becomes cloudy in air, since calcium hydroxide, like other strong bases, reacts with carbon dioxide dissolved in water:

If you continue bubbling carbon dioxide, the precipitate that has formed will dissolve, as an acidic salt is formed - calcium bicarbonate:

CaCO 3 + CO 2 + H 2 O → Ca(HCO 3) 2,

Moreover, when the solution is heated, the bicarbonate is destroyed again and a precipitate of calcium carbonate precipitates:

Ca(HCO 3) 2 →(t) CaCO 3 ↓ + CO 2 + H 2 O

Calcium hydroxide reacts with carbon monoxide at a temperature of about 400°C:

Application

  • when whitewashing premises;
  • for preparing lime mortar. Lime has been used for building masonry since ancient times. The mixture is usually prepared in the following proportion: 3-4 parts of sand (by weight) are added to 1 part of a mixture of calcium oxide (quicklime) and water. In this case, the mixture hardens according to the reaction:

Ca(OH) 2 + CO 2 → CaCO 3 ↓ + H 2 O

see also

Wikimedia Foundation. 2010.

See what “Lime water” is in other dictionaries:

    Aqueous solution of calcium hydroxide... Big Encyclopedic Dictionary

    LIME WATER, saturated solution of CALCIUM HYDROXIDE (slaked lime, Ca(OH)2). Used to detect carbon dioxide (CO2), which precipitates into a milky white precipitate as calcium carbonate (CaCO3) and rises from the bottom as... ... Scientific and technical encyclopedic dictionary Chemijos terminų aiškinamasis žodynas

    Saturated aqueous solution of calcium hydroxide Ca(OH)2 (slaked lime). 1 l I.v. at 20°C contains about 1.2 g CaO. In technology it is used as a cheap alkali. See Calcium hydroxide... Big Soviet encyclopedia

    - (Aq. Calcis) a medicinal product obtained by shaking one part of burnt lime with 10 parts of distilled water. After shaking, the water is drained and mixed with 25 parts of distilled water. It is used internally for heartburn, for English... ...

    Water calcium hydroxide solution... Natural science. encyclopedic Dictionary

    Since ancient times, they began to understand the great importance of water not only for people and all kinds of animal and plant organisms, but also for all life on Earth. Some of the first Greek philosophers even placed water at the forefront of understanding things in nature, and... ... Encyclopedic Dictionary F.A. Brockhaus and I.A. Efron

4.8 out of 5

What is calcium hydroxide? It's just lime. Regular lime for whitewashing. In construction, calcium hydroxide is called “slaked lime,” which is obtained by diluting quicklime, that is, calcium oxide, in water. If you remember the chemical formulas, this process goes like this: CaO + H2O → Ca(OH)2.

Slaked lime looks like a white powder, poorly soluble in water. But it turns out that calcium hydroxide is also a dietary supplement.

Application of calcium hydroxide in the food industry

In the food industry, calcium hydroxide is used as a food additive E526. Its action: thickener, acidity regulator, hardener, emulsifier. Let's take a closer look at all the use cases.

Emulsifier is its most popular use. The food additive E526 is part of the class of emulsifier-stabilizers, responsible for both the homogeneity and viscosity of the product. But other properties of calcium hydroxide also did not go unnoticed by the food industry.

The fact is that Ca(OH)2 is a strong base (alkali) that reacts with acids to form calcium salts. Its solution is even used to detect carbon dioxide leaks (reacting with carbon dioxide, the solution becomes cloudy). But in the food industry, this property of calcium hydroxide is used to neutralize too high acidity of the product. For example, in canning, in the production of drinks, in the production of baby food.

By the way, this supplement is considered natural, because calcium hydroxide is produced from the mineral portlandite. In Russia, E526 is permitted subject to compliance with production standards (excess calcium hydroxide is harmful to health, so its use must be controlled).

E526 food additive can be found in the following products:

  • Butter;
  • Chocolate and chocolate creams;
  • Grape juice;
  • Canned food with marinade (for example, cucumbers, mushrooms, zucchini);
  • Baby food;
  • Ice cream;
  • Dried fish.

This substance is also used for storing eggs, sweet frozen foods (to regulate acidity), and fish. If on corn flakes or baby food you see the inscription “enriched with calcium”, most likely this means E526, calcium hydroxide, or simply, lime. True, this additive is rarely used (compared to others).

Lime is also widely used in technological process desugarification of molasses (molasses). Molasses is, in fact, a waste product from sugar production, a mixture of sugar residues and salts, from which it is no longer possible to obtain sugar through the traditional crystallization process. But the technologists did not want to come to terms with the loss of some sugars, so they proposed various ways separating them from salts. Here, calcium hydroxide also came to the rescue: with the help of slaked lime, sugars are removed from the solution, the rest is filtered. And then, due to the property of calcium hydroxide to react with carbon dioxide, saccharates decompose into sugar crystals and alkaline earth salts, which easily crystallize and separate from each other.

Possible harm of calcium hydroxide

In the list of food additives, E526 is marked as safe. Is it so? What can excess calcium hydroxide cause in the body? There are entire regions that drink water supersaturated with calcium. What does this lead to? On the one hand, lime is considered a natural antiseptic. On the other hand, a violation of the acid-base balance of the body is always harmful to health and leads to disease.

Excess calcium hydroxide in food (one-time poisoning) leads to abdominal pain, vomiting, throat spasms, burning in the mouth, and a drop in blood pressure.

A constant excess of this substance leads to the fact that lime will begin to negatively affect the mucous membrane of the stomach and intestines and be deposited on the walls of blood vessels. There is also a risk of pancreatitis and kidney stones.

But in modern nutrition conditions, the problem is not an excess, but rather a lack of calcium in the body. In this case, calcium hydroxide as a dietary supplement will not affect your well-being in any way..

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Structural formula

Molecular weight: 74.094

Calcium hydroxide, Ca(OH)2 slaked lime or “fluff” is a chemical substance, a strong base. It is a white powder, poorly soluble in water.

Trivial names

  • Slaked lime - as it is obtained by “quenching” (that is, reacting with water) “quicklime” (calcium oxide).
  • Lime milk is a slurry (suspension) formed by mixing excess slaked lime with water. Looks like milk.
  • Lime water is a clear solution of calcium hydroxide obtained by filtering lime milk.

Receipt

It is obtained by reacting calcium oxide (quicklime) with water (the process is called “slaked lime”). This reaction is exothermic, releasing 16 kcal (67 kJ) per mole.

Properties

Appearance: white powder, slightly soluble in water. Calcium hydroxide is a fairly strong base, which is why the aqueous solution is alkaline. Solubility decreases with increasing temperature. Like all bases, it reacts with acids; as an alkali - is a component of the neutralization reaction (see neutralization reaction) with the formation of the corresponding calcium salts. For the same reason, a solution of calcium hydroxide becomes cloudy in air, since calcium hydroxide, like other strong bases, reacts with carbon dioxide dissolved in water. If the treatment with carbon dioxide is continued, the precipitate that has formed will dissolve, as an acidic salt is formed - calcium bicarbonate, and when the solution is heated, the bicarbonate is again destroyed and a precipitate of calcium carbonate precipitates. Calcium hydroxide reacts with carbon monoxide at a temperature of about 400 °C. How a strong base reacts with salts, but only if the reaction results in a precipitate.

Application

  • When whitewashing premises.
  • For preparing lime mortar. Lime has been used for building masonry since ancient times. The mixture is usually prepared in the following proportion: three to four parts of sand (by weight) are added to one part of a mixture of calcium hydroxide (slaked lime) and water. During the reaction, water is released. This is a negative factor, since in rooms built with lime mortar, stains remain for a long time. high humidity. In this regard, and also due to a number of other advantages over calcium hydroxide, cement has practically replaced it as a binder for building mortars.
  • For the preparation of silicate concrete. The composition of silicate concrete is similar to the composition of lime mortar, but its hardening occurs several orders of magnitude faster, since the mixture of calcium oxide and quartz sand is treated not with water, but with superheated (174.5-197.4 °C) water steam in an autoclave at a pressure of 9 -15 atmospheres.
  • To eliminate carbonate hardness of water (water softening).
  • For the production of bleach.
  • For the production of lime fertilizers and neutralization of acidic soils.
  • Causticization of sodium and potassium carbonate.
  • Leather tanning
  • Obtaining other calcium compounds, neutralizing acidic solutions (including Wastewater production), production of organic acids, etc.
  • It is registered in the food industry as a food additive E526.
  • Lime water is a clear solution of calcium hydroxide. It is used to detect carbon dioxide. When interacting with him, she becomes cloudy.
  • Lime milk is a suspension (suspension) of calcium hydroxide in water, white and opaque. It is used to produce sugar and prepare mixtures to combat plant diseases and whitewash trunks.
  • In dentistry - for disinfection of root canals of teeth.
  • In electrical engineering - when constructing grounding centers in soils with high resistance, as an additive that reduces the resistivity of the soil.
  • Lime milk is used as a base in the preparation of the classic fungicide - Bordeaux mixture.
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