Glass Glass is... Glass is one of the most ancient and, due to the variety of its properties, a material that is universal in human practice. Physico-chemically inorganic. Presentation on the topic "glass"
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Glass is... Glass is one of the most ancient and, due to the variety of its properties, a universal material in human practice. Physicochemical - inorganic matter, solid; structurally - amorphous, isotropic; aggregate all types of glasses - an extremely viscous supercooled liquid, reaching a glassy state in the process of cooling at a rate sufficient to prevent the crystallization of melts obtained in given temperature limits(from 300 to 2500 ºС), which are due to the oxide, fluoride or phosphate origin of their compositions.
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The history of glass It has not yet been reliably established how and where glass was first obtained. For a long time, the primacy in the discovery of glassmaking was recognized by Egypt, to which glass-glazed faience tiles were considered undoubted evidence. interior linings pyramids of Jesser (mid-III millennium BC); to even more early period(the first dynasty of the pharaohs) include finds of faience jewelry (see above), that is, glass existed in Egypt already 5 thousand years ago. Egyptian glassmakers melted glass on open hearths in earthenware bowls. The sintered pieces were thrown hot into the water, where they cracked, and these fragments, the so-called frits, were ground into dust by millstones and melted again. ancient vase
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Artistic glass Artistic glass is a very old craft. Not only dishes, window glass, lenses and other utilitarian items were made of glass, but also a variety of art products. Glass blowing is an operation that makes it possible to obtain glass from a viscous melt various forms- balls, vases, glasses. The most important working tool of a glassblower, his blowing tube, is a hollow metal tube 1-1.5 m long, one-third sheathed in wood and equipped with a brass mouthpiece at the end. Using a pipe, the glass blower collects molten glass from the furnace, blows it into a ball shape and molds it. Ready product they knock it off the pipe onto a pitchfork and carry it into the annealing furnace. The trace (nozzles, cap) remaining from the rebound must be removed by grinding
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The history of the modern bottle The very first bottles in the modern sense were ugly - thick-walled, lopsided, made of cloudy dirty glass with bubbles. However, they could already boast small size, a certain convenience, and therefore quickly gained popularity. But still, a lot of time passed before the bottles acquired modern harmony and noble posture. Of the first glass bottles, the most highly valued and expensive were the products of Venetian craftsmen - intricate shapes, with rich gilding and overhead, also made of glass mass, details. The heart of this glass industry was the island of Murano - because of the threat of fires in 1292, all the glass production of the Venetian Republic was transferred to it because of the threat of fires. The craft reached its peak in the 15th century and was caused by the emergence of new glass blowing technology and new methods of glass processing. At the same time, the masters of the island of Murano learned how to make not only colored, but also white (it is also “milk”) glass, which immediately became fashionable in Europe ... In those days when glassmaking developed in Venice and Venetian products became known outside the Apennine peninsulas, the local craftsmen, as well as the glassblowers of the cities of Faenza and Urbino, put a lot of effort and skill in the production of bottles. The bottles made by these craftsmen (cast in special metal molds) have become real works of art - bizarre in appearance, tall and graceful, flat or almost spherical. They were decorated with convex relief drawings depicting flowers, fruits, and even various scenes from mythology. It was in such bottles that wines, other drinks and seasonings were served on the table in rich houses. More simple bottles served to store liquid products, but they were also considered quite expensive in those days. Starting from the 17th-18th centuries, medicines and perfumes began to be stored in modern-style glass bottles. It is the same 18th century was marked by an incredible rise in the wine trade, which, in particular, was famous for the Enlightenment. Manufacturers were forced to solve the problem of exclusive branding of their products on bottles. The main problem was that appearance products invariably had to attract with their grace the whimsical gaze of a fastidious buyer. Sealing wax, which was used to cover the cork of a bottle until that time, was a short-lived material: seals were easy to fake. Around the end of the XVIII century. the custom came into fashion to mark with seals not sealing wax, but the actual wine bottle immediately before putting it on sale. In addition, the quality of the product was additionally confirmed by excise lead seals, which customs officials supplied with those sent to long way wine boxes. Somewhat later, after the Napoleonic wars, which almost undermined the export of Portuguese port wine to England, information about the contents began to be applied to the mold before the glass bottle was poured. At the same time, chemists synthesized glue, with which it became possible to attach a label to bottle glass. The further - the more: wine merchants invented the most incredible forms of bottles for bottling intoxicating drinks, and all these forms were patented. To date, bottles are one of the most mass-produced types of glass production. They are very diverse in purpose, shape, color and capacity. Bottles for wine differ quite a lot from each other: champagne, Bordeaux, Burgundy, Rhine, as well as those intended for strong and dessert wines and special wines like Tokay, port, vermouth, malaga and many others. others
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Glass bottles Glass is a very ancient packaging material: glass vessels were used in Egypt and Syria as early as three thousand years BC. e. At the same time, the technology of glass production is very static. Previously, bottles were blown using a special glass tube made of metal (most often iron) and approximately one third covered with wood. On one side of the tube was a mouthpiece, on the other - a special pear-shaped thickening for glass intake. After the tube was warmed up, it (with its thickening down) was lowered into the molten glass mass and turned so that the glass mass adhered to the “pear”. The glass blower quickly pulled out the pipe and, turning it so that the molten glass was held, inserted it into a special hollow mold made of clay or metal and began to blow hard into the mouthpiece. The resulting glass bubble filled the inside of the mold, forming a hollow bottle. By and large, the only major innovation before the beginning of the twentieth century was the invention of a hundred years BC. e. glass tube. In addition, the master was not always able to maintain the beauty of the form. The lower part of the vessel, as a rule, turned out to be more massive than the upper one, since the bottle was blown from a hot glass bubble, pulling it up to the neck. The final shape - damask, cone or rounded - was also given to the bottle by hand, "running" it on special figured surfaces made of bog oak. The bottles were heavy because the composition of the glass mass included metal salts.
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Only since 1901, when the first automatic bottle machine was patented, did the real development of the mass glass industry begin. Glass is very characteristic material. The main specificity is that it must be processed in an extremely hot and semi-liquid state. The molding or blowing operation is very fast, it should be completed in just a few seconds (in some individual cases - in a few minutes). After that, the glass loses its plasticity. By and large, bottle blowing technology has undergone only minor changes since then. Another thing is that this process is now fully automated. The molten glass mass from the glass melting furnace flows into the feeder, from where it is squeezed out in a fixed portion through a special hole and cut off with mechanical scissors. The resulting drop of a certain weight falls into the draft form of the glass-forming machine, where the neck rim is formed and the bottle body is pre-inflated. Then the draft mold is opened and the resulting workpiece is moved to the final mold, where the final formation of the product takes place. Frozen bottles go for annealing and slow cooling. The quality of annealing is determined by the term "glass thermal past". Good annealing allows you to get rid of the occurrence of internal stresses inside the glass, due to which the finished product can crumble into small pieces at the slightest impact, increase in pressure (bottling) or temperature (pasteurization).
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The presentation on the topic Glass can be downloaded absolutely free of charge on our website. Presentation subject: Chemistry. Colorful slides and illustrations will help you to interest your classmates or audience. To view the contents of the presentation, use the player, or if you want to download the presentation, click on the appropriate text under the player. The presentation contains 11 slides.
Presentation slides
Glass is…
Glass is one of the most ancient and, due to the variety of its properties, a universal material in human practice. Physico-chemically - inorganic substance, solid body; structurally - amorphous, isotropic; Aggregately, all types of glasses are an extremely viscous supercooled liquid that reaches a glassy state in the process of cooling at a rate sufficient to prevent the crystallization of melts obtained within the specified temperature ranges (from 300 to 2500 ºС), which are due to the oxide, fluoride or phosphate origin of their compositions.
History of glass
Until now, it has not been reliably established how and where glass was first obtained. For a long time, the primacy in the discovery of glassmaking was recognized by Egypt, to which the glass-glazed faience tiles of the inner facings of the Jesser pyramid (mid-III millennium BC) were considered undoubted evidence; to an even earlier period (the first dynasty of the pharaohs) are the finds of faience jewelry (see above), that is, glass existed in Egypt already 5 thousand years ago. Egyptian glassmakers melted glass on open hearths in earthenware bowls. The sintered pieces were thrown hot into the water, where they cracked, and these fragments, the so-called frits, were ground into dust by millstones and melted again.
ancient vase
glass properties
Glass is an inorganic isotropic substance, a material known and used since ancient times. It also exists in a natural form, in the form of minerals (obsidian is a volcanic glass), but in practice - most often, as a product of glassmaking - one of ancient technologies in material culture. Structurally - amorphous substance, aggregate related to the category - a solid body. In practice, there is a huge number of modifications, implying a lot of various utilitarian possibilities, determined by the composition, structure, chemical and physical properties.
Currently, materials have been developed for an extremely wide, truly universal range of applications, which are both inherent initially (for example, transparency, reflectivity, resistance to aggressive environments, beauty, and many others) and previously uncharacteristic of glass - its synthesized qualities (for example, heat resistance , strength, bioactivity, controlled electrical conductivity, etc.). Different kinds glass is used in all areas human activity: from construction, visual arts, optics, medicine - to measuring technology, high technology and astronautics, aviation and military equipment.
glass formers
Glass-forming substances include: Oxides: SiO2 B2O3 P2O5 TeO2 GeO2 Fluorides: AlF3, etc.
art glass
Art glass is a very old craft. Glass was used to make not only dishes, window glass, lenses and other utilitarian items, but also a variety of artistic products. Glass blowing is an operation that allows obtaining various shapes from a viscous melt - balls, vases, glasses. The most important working tool of a glassblower, his blowing tube, is a hollow metal tube 1-1.5 m long, one-third sheathed in wood and equipped with a brass mouthpiece at the end. Using a pipe, the glass blower collects molten glass from the furnace, blows it into a ball shape and molds it. The finished product is knocked off the tube onto a fork and carried into the annealing furnace. The trace (nozzles, cap) remaining from the rebound must be removed by grinding
vessels. They were filled manually with a charge consisting of quartz sand, soda, chalk, dolomite and other materials. Charge at high temperature turned into a transparent mass. From liquid glass mass, glassblowers blew various vessels, bottles, utensils or cylinders, from which sheets of glass were then obtained. It was the hardest work. At the age of 30 of the last century, the first bath ovens appeared in Russia for industrial production glass. The demand for it grew very quickly. Glass-making factories began to make glass. And on each - one or more bathroom furnaces that produced tons of glass per day. Modern bath stoves are large structures. The length of the furnace for the production of window glass is several tens of meters. The mixture is loaded into the furnace continuously at 10-15 tons per hour using mechanical devices. The furnace holds more than 2500 tons of glass mass and produces 350 tons of glass and more per day. Even at high temperatures, glass mass has a high viscosity, tens of thousands of times greater than water. Therefore, bubbles of gases emitted by soda, chalk and other components of the charge linger in it for a long time. In addition, hundreds of tons of viscous glass melt is difficult to mix and make homogeneous.